TRIPROPYLENE
GLYCOL
|
PRODUCT
IDENTIFICATION
|
CAS
NO. |
24800-44-0
|
|
EINECS
NO. |
246-466-0
|
FORMULA |
H(OC3H6)3OH |
MOL
WT. |
192.26 |
H.S.
CODE |
|
SMILES
|
byproduct
of propylene glycol |
TOXICITY
|
Oral
rat LD50: 10000 mg/kg |
SYNONYMS |
[(1-methyl-1,2-ethanediyl)bis(oxy)]bispropanol;
TPG;
|
2-(2-(2-Hydroxypropoxy)propoxy)-1-propanol;
1,1'-(propylenedioxy)di-2-Propanol;
1,1'-[(1-methyl-1,2-ethanediyl)bis(oxy)]bis-2-Propanol;
[(Methylethylen)bis(oxy)] Dipropanol; [Mmetiletilen)bis(oxi)]dipropanol
(Spanish); [(Méthyléthylène)bis(oxy)]
Dipropanol (French); |
CLASSIFICATION
|
SOLVENT
/ DIOLS /
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
clear
liquid |
MELTING
POINT |
-41
C |
BOILING
POINT |
265
C |
SPECIFIC
GRAVITY |
1.02 |
SOLUBILITY
IN WATER |
miscible
|
pH |
|
VAPOR
DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS |
Health:
0 Flammability: 1 Reactivity: 0 |
REFRACTIVE
INDEX
|
1.4415
- 1.4425
|
FLASH
POINT |
141
C
|
STABILITY |
Stable
under ordinary conditions |
APPLICATIONS
|
Tripropylene
Glycol, distilled by hydrolysis of PO (Propylene oxide),
is a colourless, viscous, colorless liquid
featuring
low toxicity, low volatility, slow evaporation and
water miscibility. It and its ethers are not toxic and can be
used in food, soaps
and personal care products
as well as industrial applications such as;
- Initiator for urethane polyols
- Manufacturing polyester plastics
- As a solvent and homogenising
agent for
inks
and other coloring materials
- Varnish
removers
- Hard surface cleaning formulations, and penetrating
oils
- Additive for carburettor fuels
as a lubricant and anti-freezing agent
- An ingredient of plasticizers, emulsifiers
and hydraulic fluids.
- Cooling media and a disinfectants
in cosmetics
|
SALES
SPECIFICATION |
APPEARANCE
|
clear
liquid |
ASSAY
|
99.0%
min
|
SPECIFIC
GRAVITY
|
1.015
-1.028
|
DISTILLATION
IBP |
263
C
|
DISTILLATION
DP |
280
C
|
COLOR,
APHA
|
40
max
|
ACIDITY
|
0.01%
max
|
WATERR
|
0.2%
max |
TRANSPORTATION |
PACKING |
200kgs
in drum
|
HAZARD
CLASS |
Not
regulated |
UN
NO. |
|
OTHER
INFORMATION |
European
Hazard Symbols: XI, Risk Phrases: 36/37/38, Safety Phrases:
26-36 |
GENERAL
DESCRIPTION OF PROPYLENE GLYCOL
|
Glycol: any of a class of organic chemicals characterized by having separate two
hydroxyl (-OH) groups, contribute to high water solubility, hygroscopicity and
reactivity with many organic compounds, on usually linear and aliphatic carbon
chain. The general formula is CnH2n(OH)2 or
(CH2)n(OH)2. The wider meaning names
include diols, dihydric alcohols, and dihydroxy alcohols. Polyethylene glycols
and polypropylene glycols are sometimes called polyglycols which are derived by
polymerization of ethylene oxide and propylene oxide respectively. Polyethylene
glycols are water-soluble at all molecular weights, but polypropylene glycols
become increasingly less water-soluble at high molecular weights. Mono-, di- and
tripropylene glycol, the first three members of a homologous series of propylene
glycol, are completely water and ethanol soluble; miscible with most organic
solvents including acetone, chloroform and some essential oils; soluble in 12
parts of ether. Propylene glycol is an odorless and colorless liquid; boiling
point 188 C, freezing point -39 C. Propylene glycol is prepared by hydrolysis of
propylene oxide. Large amount of propylene glycol is used in the plastics
industry for the manufacture of polyester fibers and alkyd resins. It is
used as a main ingredient in automobile antifreeze and engine-cooling liquids
and in brake and hydraulic fluids due to its useful properties of low freezing
point, involatility and low corrosive activity. It is used in the preparation of
body-care surfactants. Propylene glycol is replacing ethylene glycol and ethanol
as it is less toxic than ethylene glycol. Propylene glycol is described as a
"generally recognized as safe for use in food, cosmetics, and medicines" by
FDA. Propylene glycol USP grade is used as a non-toxic antifreeze in breweries
and dairies. It is used as a humectant in foods and cosmetics. It is used as a
solvent for colouring or flavouring agents as well as in many
oral, injectable or topical pharmaceuticals. Its
antibacterial property is applied in the preparation of sanitizing lotions.
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