TRIPROPYLENE GLYCOL


PRODUCT IDENTIFICATION

CAS NO.

24800-44-0

TRIPROPYLENE GLYCOL 

EINECS NO.

246-466-0

FORMULA H(OC3H6)3OH
MOL WT. 192.26
H.S. CODE  

SMILES

byproduct of propylene glycol

TOXICITY

Oral rat LD50: 10000 mg/kg
SYNONYMS

[(1-methyl-1,2-ethanediyl)bis(oxy)]bispropanol; TPG;

2-(2-(2-Hydroxypropoxy)propoxy)-1-propanol; 1,1'-(propylenedioxy)di-2-Propanol; 1,1'-[(1-methyl-1,2-ethanediyl)bis(oxy)]bis-2-Propanol; [(Methylethylen)bis(oxy)] Dipropanol; [Mmetiletilen)bis(oxi)]dipropanol (Spanish); [(Méthyléthylène)bis(oxy)] Dipropanol (French);

CLASSIFICATION

SOLVENT / DIOLS /

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE clear liquid
MELTING POINT -41 C
BOILING POINT 265 C
SPECIFIC GRAVITY 1.02
SOLUBILITY IN WATER

miscible

pH

 

VAPOR DENSITY  
AUTOIGNITION

 

NFPA RATINGS Health: 0 Flammability: 1 Reactivity: 0

REFRACTIVE INDEX

1.4415 - 1.4425

FLASH POINT

141 C

STABILITY Stable under ordinary conditions

APPLICATIONS

Tripropylene Glycol, distilled by hydrolysis of PO (Propylene oxide), is a colourless, viscous, colorless liquid featuring low toxicity, low volatility, slow evaporation and water miscibility. It and its ethers are not toxic and can be used in food, soaps and personal care products as well as industrial applications such as;
  • Initiator for urethane polyols
  • Manufacturing polyester plastics
  • As a solvent and homogenising agent for inks and other coloring materials
  • Varnish removers
  • Hard surface cleaning formulations, and penetrating oils
  • Additive for carburettor fuels as a lubricant and anti-freezing agent
  • An ingredient of plasticizers, emulsifiers and hydraulic fluids.
  • Cooling media and a disinfectants in cosmetics
SALES SPECIFICATION

APPEARANCE

clear liquid

ASSAY

99.0% min

SPECIFIC GRAVITY

1.015 -1.028

DISTILLATION IBP

263 C

DISTILLATION DP

280 C

COLOR, APHA

40 max

ACIDITY

0.01% max

WATERR

0.2% max
TRANSPORTATION
PACKING

200kgs in drum

HAZARD CLASS Not regulated
UN NO.  
OTHER INFORMATION
European Hazard Symbols: XI, Risk Phrases: 36/37/38, Safety Phrases: 26-36

GENERAL DESCRIPTION OF PROPYLENE GLYCOL

Glycol: any of a class of organic chemicals characterized by having separate two hydroxyl (-OH) groups, contribute to high water solubility, hygroscopicity and reactivity with many organic compounds, on usually linear and aliphatic carbon chain. The general formula is CnH2n(OH)2 or (CH2)n(OH)2. The wider meaning names include diols, dihydric alcohols, and dihydroxy alcohols. Polyethylene glycols and polypropylene glycols are sometimes called polyglycols which are derived by polymerization of ethylene oxide and propylene oxide respectively. Polyethylene glycols are water-soluble at all molecular weights, but polypropylene glycols become increasingly less water-soluble at high molecular weights. Mono-, di- and tripropylene glycol, the first three members of a homologous series of propylene glycol, are completely water and ethanol soluble; miscible with most organic solvents including acetone, chloroform and some essential oils; soluble in 12 parts of ether. Propylene glycol is an odorless and colorless liquid; boiling point 188 C, freezing point -39 C. Propylene glycol is prepared by hydrolysis of propylene oxide. Large amount of propylene glycol is used in the plastics industry for the manufacture of polyester fibers and alkyd resins. It is used as a main ingredient in automobile antifreeze and engine-cooling liquids and in brake and hydraulic fluids due to its useful properties of low freezing point, involatility and low corrosive activity. It is used in the preparation of body-care surfactants. Propylene glycol is replacing ethylene glycol and ethanol as it is less toxic than ethylene glycol. Propylene glycol  is described as a "generally recognized as safe for use in food, cosmetics, and medicines" by FDA.  Propylene glycol USP grade is used as a non-toxic antifreeze in breweries and dairies. It is used as a humectant in foods and cosmetics. It is used as a solvent for colouring or flavouring agents as well as in many oral, injectable or topical pharmaceuticals. Its antibacterial property is applied in the preparation of sanitizing lotions.